Tetra-μ2-oxido-di-μ4-peroxido-tetrakis[diphenylantimony(V)] chloroform disolvate
نویسندگان
چکیده
The title compound, [Sb(4)(C(6)H(5))(8)O(4)(O(2))(2)]·2CHCl(3), contains a tetranuclear antimony(V) core, bridged by oxide and peroxide ligands. Two cores form centrosymmetric dimers by intermolecular C-H⋯O contacts. These dimeric units are further connected by chloro-form solvent mol-ecules involved in C-H⋯O and C-H⋯Cl inter-actions into strands along [010]. The five-membered Sb(2)O(3) rings in the Sb(4)O(8) core invariably adopt envelope conformations.
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009